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Maximizing Hydrogen Electrolyzer Efficiency

Hydrogen electrolyzer production

Optimize Hydrogen Electrolyzer Production with High-Performance Fluid Systems

Hydrogen continues to gain traction as a low-carbon energy source with major potential. Here’s one point of evidence: The European Commission aims to produce 10 million tons and import 10 million tons of renewable hydrogen in the European Union by 2030. Elsewhere, analysts expect hydrogen electrolyzer sales in China to more than double in 2023 as the country continues rolling out green hydrogen projects.

Bringing hydrogen into the mainstream as an energy source depends on increased capacity and reliable production. And achieving that starts at the heart of the hydrogen production facility with optimized electrolyzers. Electrolyzers do the important work of converting water and electricity into hydrogen and oxygen. To do that job most effectively and efficiently, the electrolyzer requires reliable delivery of water and effective outflow of the resulting hydrogen and oxygen gases.

That means the fluid systems that perform these functions are of critical importance when designing new hydrogen production facilities. Let’s take a closer look at how your fluid systems can make a major impact on the safety, productivity, and profitability of a hydrogen production facility.

Two main types of electrolyzer designsKnow Your Electrolyzers

In the hydrogen production space, there are two main types of electrolyzer designs:

Alkaline Electrolyzers (AEL): Alkaline electrolysis is a mature technology that has been used for over 100 years. Operating at low temperatures, alkaline electrolysis uses a liquid alkaline solution of potassium hydroxide (KOH) or sodium hydroxide (NaOH) as an electrolyte to conduct electricity. It splits water into hydrogen and oxygen using this electrical current. It is the cheapest form of hydrogen production but comes with high maintenance costs.

Proton Exchange Membrane (PEM) Electrolyzers: PEM electrolyzers use a solid electrolyte rather than a liquid form to conduct electricity. PEM electrolyzers are generally more efficient, require less maintenance, and take up a smaller footprint than their AEL counterparts. However, PEM electrolyzers are more expensive to operate, as they require precious metals like platinum.

No matter which technology is deployed in your facility, robust fluid systems are required to handle and manage the inflow of water and the outflow of hydrogen and oxygen gasses.


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Leak Mitigation During Fluid System Installation

As a new hydrogen production facility moves toward startup, all critical fluid systems are subjected to factory acceptance testing (FAT). This process includes the inspection and equipment qualification testing of systems (or major components) conducted and documented at a supplier site. For hydrogen fluid systems, the process commonly involves flowing a benign test fluid (typically nitrogen) through the system at increasingly high pressures to determine the location and volume of any leaks.

Even small leaks can lead to inefficient use of resources as water flows into the electrolyzer. And as oxygen and hydrogen are processed out, leaks can lead to loss of valuable product and may potentially create a safety hazard. These problems also take time to fix. Minimizing leaks from the start through proper design can help set up a new hydrogen production facility for success.

One of the most common reasons for leaks upon system startup is improper installation Ana Dominguez, Engineering Services Supervisor, Swagelok Company

Notes from the Field

Ana Dominguez, Engineering Services Supervisor, Swagelok Company

One of the most common reasons for leaks upon system startup is improper installation. That’s true in hydrogen production facilities and just about any facility where fluid systems are critical parts of operation. If hydrogen producers want to minimize costs during startup, installation training can make a big impact. Installers who are equipped with the right knowledge and best practices are more likely to avoid the types of errors that can lead to leaks.

If leaks are detected during FAT…

Shutdown of system powerThe testing process must be shut down

 

System must be purgedThe system must be purged

 

Identify leak pointsOperators must identify the leak points

 

Manually repairing leaksThe leaks must be repaired via manual intervention

 

Testing must be restartedThe testing must be restarted

Hydrogen electrolyzer production plant

All of this can lead to significant unplanned time and material costs before the plant is even up and running. To mitigate leaks and associated costs, it can be beneficial to take advantage of fluid system installation training. Following established best practices during installation can help avoid issues during startup testing and costly reworking of critical fluid systems.

Maintaining Clean Hydrogen Output

It is critical that the output gases from electrolyzers for hydrogen production reach 99.9% purity. High-quality stainless steels that contain higher concentrations of chromium and nickel than ASTM requirements can more ably resist corrosion and hydrogen embrittlement.Maintaining this level of purity has as much to do with your outflow fluid systems as the electrolyzer itself.

This is a challenging proposition. High temperatures and high humidity levels inherent to the electrolysis process are conducive to the development of corrosion in lesser-quality stainless steel, which can contaminate H2 output as it travels from the electrolyzer to a storage tank. Corrosion is also a safety concern, as highly corroded tubes or fittings have greater potential for failure.

There are a few strategies you can deploy to maintain purity. High-quality gas grab sampling systems should be used to regularly analyze and monitor purity levels in your hydrogen outputs. Additionally, it’s important to be confident in your materials selection. High-quality stainless steels that contain higher concentrations of chromium and nickel than ASTM requirements can more ably resist corrosion and hydrogen embrittlement.

Maximizing Your Electrolyzer Productivity

Properly installed, high-quality inflow and outflow fluid systems can help electrolyzers meet their full potential, helping you to maximize productivity.

Not only does leak-tightness help you avoid costly reworks during Factory Acceptance Testing, but it can also help prevent unforeseen maintenance issues and related downtime over the longer term. With reliable inflows and clean outflows, you can maintain process efficiency and lower your total cost of ownership over the life of the production facility. Which is even more reason to optimize your electrolyzer’s supporting fluid systems.

It is critical to select high-quality components and assemblies engineered specifically for hydrogen at the beginning of your production to help get your facility up and running faster, more safely, and positioned for long-term productivity. If you need assistance, reach out to a fluid system component provider with experience designing hydrogen systems.

Hydrogen production depends on reliable fluid transfer

Knut Marker, Technical Sales Advisor, Swagelok NorwayNotes from the Field

Knut Marker, Technical Sales Advisor, Swagelok Norway

Hydrogen production really is a new frontier. There’s no established blueprint for how to reliably and cost-effectively bring a new plant online. But we do know that hydrogen production depends on reliable fluid transfer—and that is a discipline with proven best practices that we can apply to help hydrogen plants minimize leaks, safety challenges, and maintenance issues.

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